Inorganic Chemistry 310-ERS-CHNE

LECTURE:
1. Occurrence of elements, periodicity of physicochemical properties. Structure of elements and inorganic compounds.
2. Classification of inorganic compounds.
3. Hydrogen and hydrides.
4. General characteristics of the elements of the block s. Physicochemical properties, methods of obtaining and using of the elements from lithium and beryllium group.
5. Characteristics of the elements of the block p. Boron group - minerals, methods of obtaining, properties. Structure and classification of borates, borazine, aluminothermic reaction.
6. Carbon group - allotropic species of coal, classification of carbides, carbonyls, silanes, siloxanes, silicates and zeolites.
7. Nitrogen group - allotropic variants and physicochemical properties of phosphorus, compounds of nitrites with oxygen, hydrogen, halogens, sulfur. Oxides and oxygen acids of nitrogen, phosphorus, antimony, bismuth and arsenic.
8. General characteristics of oxygen group. Structure of molecules, allotropy and physical and chemical properties of the elements from the oxygen group.
9. Elements from the fluorine group - occurrence in nature, obtaining, physical and chemical properties, application.
10. Properties of the elements from the helium group; superfluid, Bartlett's synthesis, helium compounds.
11. Electron configurations, oxidation degrees, physical and chemical properties, metal complexes of the elements from the block d.
12. Interstitial metal compounds of transition groups - hydrides, carbides, nitrides, borides.
13. Physical and chemical properties and use of zinc and its compounds.
14. General characteristics of lanthanides and scandens. Actinides and transuranic elements.

SEMINAR:
The subject of the seminar in terms of content and order of execution is consistent with the lecture program. Student solves problem tasks related to the issues.
1. General characteristics of the elements.
2. Principles of the elements of the main groups (hydrogen, lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine and helium groups): occurrence, physical and chemical properties, important compounds, receiving and application.
3. Characteristics of the elements of transition groups (scandium, titanium, vanadium, chromium, manganese, copper and zinc groups): occurrence, methods of obtaining, reactivity and more important compounds.
4. Properties of ferrous group triads and light and heavy platinum group triads.
5. Comparison of the elements of blocks s and p with elements of block d and f.

LABORATORY:
1. Introduction to the exercises from inorganic chemistry, regulations of the workshop.
2. Determination of the solubility product of PbCl2 by precipitation titration and the conductometric method.
3. Extraction - spectrophotometric study of the system: picric acid - promazine.
4. Determination of the average number of coordination and constant formation of silver complex with ammonia.
5. Determination of the dissociation constant of blue thymol.
6. The stability constant of the complex [Ni(NH3)4]2+ and [Cu(NH3)4]2+ determined by potentiometric method.
7. Chemical preparation of:
- hydrated chromium (III) and potassium sulphate CrK(SO4)2·12H2O
- aluminum-potassium alum AlK(SO4)2·12 H2O
- ferrous ammonium sulphate - Mohra salt (NH4)2Fe(SO4)2·6H2O.
8. Examination of purity of previously obtained alum and determination yield of reaction.
9. Complex compounds - preparation of aminocomplexes, hydroxocomplexes, halogencomplexes, chelate compounds and preparations trans – [Co(en)2(NO2)2]NO3.
10. Selected properties of some elements of group d: iron, chromium, manganese.
11. Examination of oxygen binding systems and atypical chemical reactions:
- Landolt's clock reaction;
- Harcourt reaction;
- oscillatory reaction using salt Mn (II).
12. Selected issues in bioinorganic chemistry:
- isolation of chlorophyll from selected vegetable plants;
- protonation processes: titration of natural and synthesis porphyrin.
13. The effect of pH on Cu (II) binding by glycylglycine in aqueous solution.